Application of antimonide diode lasers in photoacoustic spectroscopy.
نویسندگان
چکیده
First investigations of photoacoustic (PA) spectroscopy (PAS) of methane using an antimonide semiconductor laser are reported. The laser fabrication is made in two steps. The structure is firstly grown by molecular beam epitaxy, then a metallic distributed-feedback (DFB) grating is processed. The laser operates at 2371.6 nm in continuous wave and at room temperature. It demonstrates single-mode emission with typical tuning coefficients of 0.04 nm mA(-1) and 0.2 nm K(-1). PA detection of methane was performed by coupling this laser into a radial PA cell. A detection limit of 20 ppm has been achieved in a preliminary configuration that was not optimised for the laser characteristics.
منابع مشابه
Ultrabroadband Solid-state Lasers in Trace Gas Sensing
Application of ultrabroadband Cr2+-doped mid-infrared lasers to sensitive molecular spectroscopy in the 2–3 μm wavelength range is demonstrated using two different techniques: scanning photoacoustic spectroscopy and intracavity absorption spectroscopy. It is shown, that the broad gain bandwidth is a crucial parameter, allowing multicomponent analysis and extreme sensitivity down to 10−5 mbar of...
متن کاملNovel method for wavelength locking of tunable diode lasers based on photoacoustic spectroscopy
متن کامل
Novel Helmholtz-based photoacoustic sensor for trace gas detection at ppm level using GaInAsSb/GaAlAsSb DFB lasers.
A new and compact photoacoustic sensor for trace gas detection in the 2-2.5 microm atmospheric window is reported. Both the development of antimonide-based DFB lasers with singlemode emission in this spectral range and a novel design of photoacoustic cell adapted to the characteristics of these lasers are discussed. The laser fabrication was made in two steps. The structure was firstly grown by...
متن کاملSpectroscopic gas analyzers based on indium-phosphide, antimonide and lead-salt diode-lasers.
Currently available semiconductor lasers for spectroscopy in the near- and mid-infrared region based on direct band-to-band transitions as gallium-arsenide, indium-phosphide, antimonides and lead-salt containing compounds will be discussed together with the main features of different tunable diode-laser absorption spectrometers for trace gas analysis. Measurements of atmospheric carbon dioxide ...
متن کاملTunable Diode Lasers (TDL) for Spectroscopy and Environmental Monitoring
The current status of III-V tunable diode lasers (TDLs) emitting between 1 -5pm wavelengths for spectroscopy and chemical analysis is described. Single mode distributed feedback (DFB) strained layer lnGaAs(P) lasers grown on lnP substrates with emission wavelength from 1.2 to 2.06 pm have been developed at JPL. DFB ridge waveguide lasers at 2,06pm have operated continuous wave (CW) up to 50°C w...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
دوره 60 14 شماره
صفحات -
تاریخ انتشار 2004